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From Law 12; Fouls and Misconduct are penalized as follows
If the ball is still in play, and a goalkeeper who is in his own penalty area deliberately throws the ball at an opponent who is standing outside of the penalty area, then you must award a penalty to the opponent's team. The offence of throwing the ball commenced inside the goalkeeper's penalty area, and is a penal offence, hence the award of the penalty kick against the goalkeeper. It does not matter where the opponent is standing (inside or outside of the goalkeeper's penalty area) or whether the ball hits the opponent or not. Caution or send-off the goalkeeper depending on the severity of the throw.
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